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- Hexagonal boron nitride: an indirect bandgap semiconductor with unique opto-electronic properties hal link

Auteur(s): Cassabois G.(Corresp.)

Conférence invité: 25th International Symposium "Nanostructures: Physics and Technology" (NANO2017) (Saint-Petersbourg, RU, 2017-06-27)


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Résumé:

I will discuss our recent studies showing that the optical response in hBN displays prominent evidence for phonon-assisted optical transitions, with a very unusual phenomenology. By two-photon spectroscopy, we demonstrated that the intrinsic optical properties at the band edge are characteristic of an indirect bandgap material. Polarization-resolved experiments with a detection from the sample edge allowed us to showthat the phonon symmetries can be traced back in the optical response. I will further highlight the unique properties of this material where the optical response is tailored by the phonon group velocities in the middle of the Brillouin zone. I will finally present optical characterization results of the promising high-temperature MBE growth of hBN, in collaboration with Nottingham University.