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(468) Production(s) de l'année 2016
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Selectivity against proton in cation permeable hybrid solid state membrane
Auteur(s): Picaud Fabien, Boukari Khaoula, Balme Sebastien, Janot Jean marc, Henn F.
(Article) Publié:
Computational Materials Science, vol. 111 p.380-386 (2016)
DOI: 10.1016/j.commatsci.2015.09.044
WoS: WOS:000364164400052
4 Citations
Résumé: Theoretical investigations based principally on Monte Carlo calculations were conducted to interpret the hindered mobility of protons which was experimentally observed in a hybrid biological/artificial nanopore constituted of the ion bio-channel gramicidin A confined inside an artificial solid-state nanopore. We show that this experimental outcome may result from the high concentration of gramicidin A that progressively diminishes the transfer of proton from one side to the other of the nanopore. More, using molecular dynamic simulations data we demonstrate that the water molecules are repelling from the gramicidin structure outside the nanopore, leading to a strong decrease of the proton transfer.
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Biomimetic solution against dewetting in a highly hydrophobic nanopore
Auteur(s): Picaud Fabien, Paris Guillaume, Gharbi Tijani, Balme Sébastien, Lepoitevin Mathilde, Tangaraj Vidhyadevi, Bechelany Mikhael, Janot Jean marc, Balanzat Emmanuel, Henn F.
(Article) Publié:
Soft Matter, vol. 12 p.4903 - 4911 (2016)
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Evidence of selective cation transport through sub-2 nm single-walled carbon nanotubes
Auteur(s): Yazda K., Tahir S., Michel T., Henn F., Jourdain V.
(Article) Publié:
Mrs Advances, vol. 1 p.2079-2084 (2016)
Ref HAL: hal-01928862_v1
DOI: 10.1557/adv.2016.323
WoS: WOS:000412635300009
Exporter : BibTex | endNote
Résumé: The electrophoretic transport of ions through single wall carbon nanotubes (SWCNTs) of diameters between 1.2 and 1.8 nm was studied for different monovalent chloride salts using microfluidic devices incorporating either a single or a few CNTs in parallel. The ionic conductance was found to be about one order of magnitude higher than expected from a simple electro-migration behavior without any surface effect. Importantly, the ionic conductance measured for different cations did not scale with their bulk electrophoretic mobility thus indicating a probable selective cation transport through these sub-2 nm SWCNTs. The transport of Na+ was notably found to be favored in comparison to that of Li+ and Cs+ or K+ . These results highlight the influence of steric and surface effects induced by the nano-confinement on the transport of ions through sub-2 nm SWCNTs.
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Hole Fermi surface in Bi2Se3 probed by quantum oscillations
Auteur(s): Piot B.A., Desrat W., Maude Duncan Kennedy, Orlita M., Potemski M., Martinez Garcia Gines, Hor Y.S.
(Article) Publié:
Physical Review B, vol. 93 p.155206 (2016)
Texte intégral en Openaccess :
Ref HAL: hal-01924991_v1
DOI: 10.1103/PhysRevB.93.155206
WoS: 000374948400008
Exporter : BibTex | endNote
8 Citations
Résumé: Transport and torque magnetometry measurements are performed at high magnetic fields and low temperatures in a series of p-type (Ca-doped) Bi2Se3 crystals. The angular dependence of the Shubnikov-de Haas and de Haas-van Alphen quantum oscillations enables us to determine the Fermi surface of the bulk valence band states as a function of the carrier density. At low density, the angular dependence exhibits a downturn in the oscillations frequency between 0◦ and 90◦, reflecting a bag-shaped hole Fermi surface. The detection of a single frequency for all tilt angles rules out the existence of a Fermi surface with different extremal cross sections down to 24 meV. There is therefore no signature of a camelback in the valence band of our bulk samples, in accordance with the direct band gap predicted by GW calculations.
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Crak free hybrid aerogel cells as home matrix for liquids
Auteur(s): Etienne P., Etienne-Calas S., Courson R., Cano Jean-Paul, Biver Claudine
Conference: International Seminar on Aerogels (Nice, FR, 2016-09-22)
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Conduction electrons in acceptor-doped GaAs/GaAlAs heterostructures: a review
Auteur(s): Zawadzki W, Raymond A., Kubisa M
(Article) Publié:
Semiconductor Science And Technology, vol. 31 p.053001 (2016)
Texte intégral en Openaccess :
Ref HAL: hal-01922750_v1
DOI: 10.1088/0268-1242/31/5/053001
WoS: 000375570500001
Exporter : BibTex | endNote
4 Citations
Résumé: We review magneto-optical and magneto-transport effects in GaAs/GaAlAs heterostructures doped in GaAlAs barriers with donors, providing two-dimensional (2D) electron gas (2DEG) in GaAs quantum wells (QWS), and additionally doped with smaller amounts of acceptors (mostly Be atoms) in the vicinity of 2DEG. One may also deal with residual acceptors (mostly C atoms). The behavior of such systems in the presence of a magnetic field differs appreciably from those doped in the vicinity of 2DEG with donors. Three subjects related to the acceptor-doped heterostructures are considered. First is the problem of bound states of conduction electrons confined to the vicinity of negatively charged acceptors by the joint effect of a QW and an external magnetic field parallel to the growth direction. A variational theory of such states is presented, demonstrating that an electron turning around a repulsive center has discrete energies above the corresponding Landau levels. Experimental evidence for the discrete electron energies comes from the work on interband photo-magneto-luminescence, intraband cyclotron resonance and quantum magneto-transport (the Quantum Hall and Shubnikov–de Haas effects). An electron rain-down effect at weak electric fields and a boil-off effect at strong electric fields are introduced. It is demonstrated, both theoretically and experimentally, that a negatively charged acceptor can localize more than one electron. The second subject describes experiment and theory of asymmetric quantized Hall and Shubnikov–de Haas plateaus in acceptor-doped GaAs/GaAlAs heterostructures. It is shown that the main features of the plateau asymmetry can be attributed to asymmetric density of Landau states in the presence of acceptors. However, at high magnetic fields, the rain-down effect is also at work. The third subject deals with the so-called disorder modes (DMs) in the cyclotron resonance of conduction electrons. The DMs originate from random distributions of negatively charged acceptor ions whose potentials provide effective QWs trapping the conduction electrons. This results in an upward energy shift of the DM as compared to the cyclotron resonance. Theory and experimental characteristics of DMs are discussed. A similarity between acceptor-doped heterostructures and 2D systems with antidots is briefly described. In conclusion, we mention weaker points in the research on acceptor-doped heterostructures and indicate possible subjects for further investigation. An effort has been made to quote all important works on the subject.
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