Ref HAL: hal-01369699_v1
Exporter : BibTex | endNote
Résumé:

The interface between a liquid and a fluid affects dramatically both the interactions and the motion of colloidal particles. In this talk, the impact of partial wetting dynamics on the motion of passive and active colloids will be presented. First, experimental results on the Brownian dynamics of micrometric spherical silica colloids andpolymeric ellipsoids trapped at a planar air-water interface will be described. Partial wetting defines a contact angle which sets the immersion depth of the colloid. Particle motion is confined in the interfacial plane. For spherical colloids, the contact angle is finely tuned in the range 30°-140° by surface treatments and measured in situ. Translational and rotational diffusion coefficients of colloids trapped at the water interface are obtained by particle tracking video-microscopy. Counter-intuitively, the friction felt by the colloid increases when the contact angle increases; i.e. when particles are less immersed in water and more in air, which has a negligible viscosity. To explain the slowing down of the translational motion for spheres and rotational diffusion for ellipsoids, an extra friction term originating from contact line fluctuations will be introduced.The second part of the talk deals with the motion of isolated active Janus colloids at the surface of water. Spherical catalytic Janus colloids have been prepared coating half surface of silica particles by a thin platinum layer. Immersion depth of the Janus colloids as well as their orientation with respect to the water surface reveal thecomplex wetting properties of Janus particles. The active motion of Janus colloids at the interface in the presence of various concentration of hydrogen peroxide has been studied. The types of trajectories, directional and circular ones observed revealed the effective force and torque induced by the catalytic decomposition of H2O2. At the water surface, active colloids perform more persistent directional motions as compared to the motions performed in the bulk. This has been interpreted as due to the loss of degrees of freedom resulting from the confinement at interfaceand also to the partial wetting conditions that possibly bring new contributions to the rotational friction at interface.

Ref HAL: hal-01369691_v1
Exporter : BibTex | endNote
Résumé:

Janus colloidal particles show remarkable properties in terms of surface activity, self-assembly and wetting. Moreover they can perform autonomous motion if they can chemically react with the liquid in which they are immersed. In order to understand the self-propelled motion of catalytic Janus colloids at the air-water interface, wetting and the orientation of the catalytic surface are important properties to be investigated. Wetting plays a central role in active motion since it determines the contact between fuel and catalytic surface as well as the efficiency of transduction of chemical reaction into motion. Active motion is not expected to occur either when the catalytic face is completely out of the aqueous phase or when the Janus boundaries are parallel to the interfacial plane. The design of a Janus colloid possessing two hydrophilic faces is required to allow the catalytic face to react with the fuel (e.g. H2O2 for Platinum) in water and to permit some rotational freedom of the Janus colloid in order to generate propulsion parallel to the interfacial plane.Here, we discuss some theoretical aspects that should be accounted when studying Janus colloids at the surface of water. The free energy of ideal Janus colloidal particles at the interface is modeled as a function of the immersion depth and the particle orientation. Analytical expressions of the energy profiles are established. Energetic aspects are then discussed in relation to the particle ability to rotate at the interface. By introducing contact angle hysteresis we describe how the effects of contact line pinning modifies the scenario described in the ideal case. Experimental observations of the contact angle hysteresis of Janus colloids at the interface reveal the effect of pinning; and orientations of silica particles half covered with a platinum layer at the interface do not comply with the ideal scenarios. Experimental observations suggest that Janus colloids at the fluid interface behave as kinetically driven system, where the contact line motion over defects decorating the Janus faces rules the orientation and rotational diffusion of the particle.

Ref HAL: hal-01366306_v1
Ref Arxiv: 1607.02271
DOI: 10.1021/acsmacrolett.6b00516
WoS: 000385913800002
Ref. & Cit.: NASA ADS
Exporter : BibTex | endNote
6 Citations
Résumé:

We investigate the nucleation and propagation of cracks in self-assembled viscoelastic fluids, which are made of surfactant micellesreversibly linked by telechelic polymers. The morphology of the micelles can be continuously tuned, from spherical to rodlike towormlike, thus producing transient double networks when the micelles are sufficiently long and entangled and transient singlenetworks otherwise. For a single network, we show that cracks nucleate when the sample deformation rate involved is comparable tothe relaxation time scale of the network. For a double network, by contrast, significant rearrangements of the micelles occuras a crack nucleates and propagates. We show that birefringence develops at the crack tip over a finite length, ξ, whichcorresponds to the length scale over which micelle alignment occurs. We find that ξ is larger for slower cracks, suggesting anincrease of ductility.

Ref HAL: hal-01355947_v1
DOI: 10.1103/PhysRevE.94.012602
WoS: WOS:000379724600011
Exporter : BibTex | endNote
8 Citations
Résumé:

We study the dynamics of individual polystyrene ellipsoids of different aspect ratios trapped at the air-water interface. Using particle tracking and in situ vertical scanning interferometry techniques we are able to measure translational drags and the protrusion in air of the ellipsoids. We report that translational drags on the ellipsoid are unexpectedly enhanced: despite the fact that a noticeable part of the ellipsoid is in air, drags are found larger than the bulk one in water.

Ref HAL: hal-01341661_v1
Exporter : BibTex | endNote
Résumé:

The mechanical properties of amorphous solids such as glasses or gels are currently a topic of intense research, with implications in material science as well in fundamental condensed matter physics. At the macroscopic scale, a distinctive feature of these materials is the slow plastic deformation that is observed when they are subject to a step stress. Remarkably, this slow creep regime is often interrupted by the sudden failure of the material, with no macroscopic precursors.Recent works focus on the interplay between irreversible rearrangements at the microscopic level, resulting from an applied deformation or stress, and the macroscopic mechanical behavior. In fact, even though material failure is ubiquitous in our everyday life, the underlying microscopic mechanisms are still not well understood, mainly because the direct observation of its precursors at the particle level is experimentally very challenging in atomic or molecular materials.In this work, we study the microscopic dynamics of a model colloidal gel under load, by coupling a small angle light scattering apparatus to a custom stress-controlled shear cell. We find that the gel creep consists of three regimes. Initially, non-affine displacements grow linearly with strain. These non-affine dynamics are fully reversible upon removing the applied stress, and are associated to heterogeneity of the local gel elasticity. In the second regime, non-affine displacements grow much slower with strain, but are associated to irreversible rearrangements. In the third regime, a sharp acceleration of the dynamics at small length scale is observed. These rearrangements are a dynamic precursor of material failure; remarkably they occur thousands of seconds before the macroscopic yielding of the gel.

Ref HAL: hal-01332389_v1
Exporter : BibTex | endNote
Résumé:

We propose a quantitative approach to probe the spatial heterogeneities of interactions in macromolecular gels, based on a combination of small angle X-ray (SAXS) and neutrons (SANS) scattering. We investigate the structure of model gluten protein gels and show that the gels display radically different SAXS and SANS profiles when the solvent is (at least partially) deuterated. The detailed analysis of the SANS signal as a function of the solvent deuteration demonstrates heterogeneities of sample deuteration at different length scales. The progressive exchange between the protons (H) of the proteins and the deuteriums (D) of the solvent is inhomogeneous and 60 nm large zones that are enriched in H are evidenced. In addition, at low protein concentration, in the sol state, solvent deuteration induces a liquid/liquid phase separation. Complementary biochemical and structure analyses show that the denser protein phase is more protonated and specifically enriched in glutenin, the polymeric fraction of gluten proteins. These findings suggest that the presence of H-rich zones in gluten gels would arise from thepreferential interaction of glutenin polymers through a tight network of non-exchangeable intermolecular hydrogen bonds.