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- Nanocomposites with both structural and porous hierarchy synthesized from Pickering emulsions doi link

Auteur(s): Avendano Carlos, Brun Nicolas, Mourad Eleonore, Fontaine Olivier, Sarroste Christine Labrugere, Baccour Mohamed, In M., Mehdi Ahmad, Stocco A., Vioux Andre

(Article) Publié: New Journal Of Chemistry, vol. 40 p.4344-4350 (2016)


Ref HAL: hal-01329849_v1
DOI: 10.1039/c5nj03248b
WoS: WOS:000375586400041
Exporter : BibTex | endNote
3 Citations
Résumé:

Commercial carboxymethylcellulose was used to prepare dispersible multi-walled carbon nanotubes-based composites. These composites were employed to prepare Pickering oil-in-water emulsions. Emulsion-templated macroporous materials were then prepared by embedding the oil droplets into a polymer resin arising from the polycondensation of furfural and phloroglucinol within the continuous aqueous phase in the presence of FeCl3 as catalyst. Polymerization afforded organic–inorganic nanocomposite materials in the form of capsules. After pyrolysis, highly microporous, magnetic and electrically conductive micrometric capsules could be obtained. This approach opens interesting prospects for catalysis, separation and electrochemistry applications.