Reply to 'Strongly-driven Re + CO2 redox reaction at high-pressure and high-temperature'.

Double-walled carbon nanotubes (DWCNT) are made of two concentric and weakly van der Waals coupled single-walled carbon nanotubes (SWCNT), also called layers. DWCNTs are the simplest systems for studying the mechanical and electronic interactions between concentric carbon layers. In this communication, we review recent results concerning the intrinsic features of phonons of DWCNTs obtained from Raman experiments performed on index-identified DWCNTs. The effect of the interlayer distance on the strength of the mechanical coupling between the layers, and thus on the frequencies of the Raman-active modes, namely the radial breathing-like modes (RBLM) [1] and G-modes [2], are evidenced and discussed.

! abstract The mechanisms of methane adsorption in (i) homogeneous carbon slit pores of widths between 1 nm and 2 nm and (ii) heterogeneous MOF pores of similar unit cell sizes have been compared. We discuss the mechanism of layering transition in subcritical conditions, for temperatures between 80 K and 180 K. The layer formation is strongly temperature-dependent. In slit pores it varies from a sharp adsorption at low temperatures to a more continuous uptake at higher temperatures. The pore size defines the number of adsorbed layers: the 1 nm pore allows adsorption of 2 layers while the 2 nm pore allows adsorption of 5 layers of methane molecules. We compare this behavior with the mechanism of adsorption in two MOFs, IRMOF-1 and IRMOF-16, with strongly heterogeneous walls (both structurally and energetically). This comparison allows us to discuss separately the influence of wall topology and intermolecular interactions on the mechanism of layering.

The melting transition of methane adsorbed in nanopores has been studied and compared in two types of structures: carbon slits pores and SURMOF square shaped channels. We show that the nano-confinement not only modifies the temperatures of phase transformation but also induces strong space heterogeneity of the adsorbate. We emphasize the role of the structural heterogeneity on the mechanism of melting: in nanometric pores, each adsorbed layer exhibits different mechanism of structural transformations and the notion of a unique transition temperature is not well defined.

We present the results of extensive fully atomistic molecular dynamics (MD) simulations of tetracosane (C24H50) bilayer and trilayer systems adsorbed onto the basal plane of graphite. At low temperature, both layers of the bilayer exist in well-defined solid phases. With increasing temperature, the system exhibits separated smectic phases that eventually lead to melting. During this process, we observed a strong interlayer translational correlation and mobility between layers; however, the upper layer presents more intra- (chain) and intermolecular disorder because of a lack of confinement and a greater distance to the graphite substrate. Simulations of the perpendicular trilayer patch show that gauche defects provide the main mechanism for spreading of the bottom and outer perimeter of the patch in the solid, leading to the ultimate collapse of the patch with increasing temperature and formation of a flat (parallel) trilayer that melts at a higher temperature than the bilayer structure. The wide variety of structural order parameters, thermodynamic functions, and probability distributions we employed provide a clear picture of the roles of gauche defects, confinement, and interlayer correlation in the phases and phase transitions exhibited by these confined organic layers.

The efficient storage and transportation of natural gas is one of the most important enabling technologies for use in energy applications. Adsorption in porous systems, which will allow the transportation of high-density fuel under low pressure, is one of the possible solutions. We present and discuss extensive grand canonical Monte Carlo (GCMC) simulation results of the adsorption of methane into slit-shaped graphitic pores of various widths (between 7 angstrom and 50 angstrom), and at pressures P between 0 bar and 360 bar. Our results shed light on the dependence of film structure on pore width and pressure. For large widths, we observe multi-layer adsorption at supercritical conditions, with excess amounts even at large distances from the pore walls originating from the attractive interaction exerted by a very high-density film in the first layer. We are also able to successfully model the experimental adsorption isotherms of heterogeneous activated carbon samples by means of an ensemble average of the pore widths, based exclusively on the pore-size distributions (PSD) calculated from subcritical nitrogen adsorption isotherms. Finally, we propose a new formula, based on the PSD ensemble averages, to calculate the isosteric heat of adsorption of heterogeneous systems from singlepore-width calculations. The methods proposed here will contribute to the rational design and optimization of future adsorption-based storage tanks.