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Production scientifique
Matière Molle
(105) Production(s) de l'année 2018
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On the effect of local sample slope during modulus measurements by contact-resonance atomic force microscopy
Auteur(s): Heinze K., Arnould Olivier, Delenne Jean-Yves, Lullien-Pellerin V., Ramonda M., George M.
(Article) Publié:
Ultramicroscopy, vol. 194 p.78 - 88 (2018)
Texte intégral en Openaccess :
Ref HAL: hal-01869770_v1
DOI: 10.1016/j.ultramic.2018.07.009
WoS: 000450281700010
Exporter : BibTex | endNote
1 Citation
Résumé: Contact-resonance atomic force microscopy (CR-AFM) is of great interest and very valuable for a deeper understanding of the mechanics of biological materials with moduli of at least a few GPa. However, sample surfaces can present a high topography range with significant slopes, where the local angle can be as large as ± 50°. The non-trivial correlation between surface slope and CR-frequency hinders a straightforward interpretation of CR-AFM indentation modulus measurements on such samples. We aim to demonstrate the significant influence of the surface slope on the CR-frequency that is caused by the local angle between sample surface and the AFM cantilever and present a practical method to correct the measurements. Based on existing analytical models of the effect of the AFM set-up's intrinsic cantilever tilt on CR-frequencies, we compute the non-linear variation of the first two (eigen)modes CR-frequency for a large range of surface angles. The computations are confirmed by CR-AFM experiments performed on a curved surface. Finally, the model is applied to directly correct contact modulus measurements on a durum wheat starch granule as an exemplary sample.
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Nanoparticle self-assembly: from interactions in suspension to polymer nanocomposites
Auteur(s): Genix A.-C., Oberdisse J.
(Article) Publié:
Soft Matter, vol. 14 p.5161-5179 (2018)
Texte intégral en Openaccess :
Ref HAL: hal-01850465_v1
PMID 29893402
DOI: 10.1039/c8sm00430g
WoS: WOS:000436574000001
Exporter : BibTex | endNote
19 Citations
Résumé: Recent experimental results using in particular small-angle scattering to characterize the self-assembly of mainly hard spherical nanoparticles into higher ordered structures ranging from fractal aggregates to ordered assemblies are reviewed. The crucial control of interparticle interactions is discussed, from chemical surface-modification, or the action of additives like depletion agents, to the generation of directional patches and the use of external fields. It is shown how the properties of interparticle interactions have been used to allow inducing and possibly controlling aggregation, opening the road to the generation of colloidal molecules or potentially metamaterials. In the last part, studies of the microstructure of polymer nanocomposites as an application of volume-spanning and stress-carrying aggregates are discussed.
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Size-characterization of natural and synthetic polyisoprenes by Taylor dispersion analysis
Auteur(s): Biron Jean-Philippe, Bonfils Frédéric, Cipelletti L., Cottet Hervé
(Article) Publié:
Polymer Testing, vol. 66 p.244-250 (2018)
Texte intégral en Openaccess :
Ref HAL: hal-01837505_v1
DOI: 10.1016/j.polymertesting.2018.01.017
WoS: 000428824000029
Exporter : BibTex | endNote
Résumé: Non-aqueous Taylor dispersion analysis (TDA) was used for the size-characterization of natural and synthetic polyisoprenes (4 × 103–2 × 106 g/mol molar mass). Not only the weight-average hydrodynamic radius (Rh), but also the probability distribution of the hydrodynamic radius, were both derived from the Taylorgrams by a simple integration of the elution profile and by a more sophisticated constrained regularized linear inversion of the Taylorgram, respectively. Results in terms of size characterization (hydrodynamic radii between 2 and 100 nm) were compared to size exclusion chromatography coupled to a refractive index-based mass detector. Multimodal size distributions were resolved by TDA for industrial and natural polyisoprenes, with the advantage over the chromatographic technique that, in TDA, there is no abnormal elution of microaggregates (hydrodynamic radii ∼ 40–50 nm). Considering the importance and the difficulty of characterizing polyisoprene microaggregates, TDA appears as a promising and simple technique for the characterization of synthetic and natural rubber.
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Overcharging and reentrant condensation of thermoresponsive ionic microgels
Auteur(s): Truzzolillo D., Sennato Simona, Sarti Stefano, Casciardi Stefano, Bazzoni Chiara, Bordi Federico
(Article) Publié:
Soft Matter, vol. 14 p.4110 - 4125 (2018)
Texte intégral en Openaccess :
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Multistep building of a soft plant protein film at the air-water interface
Auteur(s): Poirier A., Banc A., Stocco A., In M., Ramos L.
(Article) Publié:
Journal Of Colloid And Interface Science, vol. 526 p.337 - 346 (2018)
Texte intégral en Openaccess :
Ref HAL: hal-01788790_v1
PMID 29751267
DOI: 10.1016/j.jcis.2018.04.087
WoS: 000436900400034
Exporter : BibTex | endNote
20 Citations
Résumé: Gliadins are edible wheat storage proteins well known for their surface active properties. In this paper, we present experimental results on the interfacial properties of acidic solutions of gliadin studied over 5 decades of concentrations, from 0.001 to 110 g/L. Dynamic pendant drop tensiometry reveals that the surface pressure of gliadin solutions builds up in a multistep process. The series of curves of the time evolution of collected at different bulk protein concentrations C can be merged onto a single master curve when is plotted as a function of t where t is the time elapsed since the formation of the air/water interface and is a shift parameter that varies with C as a power law with an exponent 2. The existence of such time-concentration superposition, which we evidence for the first time, indicates that the same mechanisms govern the surface tension evolution at all concentrations and are accelerated by an increase of the bulk concentration. The scaling of with C is consistent with a kinetic of adsorption controlled by the diffusion of the proteins in the bulk. Moreover, we show that the proteins adsorption at the air/water interface is kinetically irreversible. Correlated evolutions of the optical and elastic properties of the interfaces, as probed by ellipsometry and surface dilatational rheology respectively, provide a consistent physical picture of the building up of the protein interfacial layer. A progressive coverage of the interface by the proteins occurs at low . This stage is followed, at higher , by conformational rearrangements of the protein film, which are identified by a strong increase of the dissipative viscoelastic properties of the film concomitantly with a peculiar evolution of its optical profile that we have rationalized. In the last stage, at even higher surface pressure, the adsorption is arrested; the optical profile is not modified while the elasticity of the interfacial layer dramatically increases with the surface pressure, presumably due to the film ageing.
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Keynote lecture: Fracture propagation in polymeric transient networks
Auteur(s): Ligoure C.
Conférence invité: Annual European Rheology Conference (AERC) 2018 (Sorrente, IT, 2018-04-17)
Ref HAL: hal-01779573_v1
Exporter : BibTex | endNote
Résumé: We investigate the fracture nucleation and propagation of reversible double transient networks, constituted of water solutions of entangled surfactant wormlike micelles reversibly linked by various amounts of telechelic polymers thus producing transient double
networks when the micelles are sufficiently long and entangled. Two different geometries of fracture are considered: (i) For a filament stretching geometry, we provide a state diagram that delineates the regime of fracture without necking of the filament from the regime where no fracture or break-up has been observed. We show that filaments fracture when stretched at a rate larger than the inverse of the slowest relaxation time of the networks. We quantitatively demonstrate that dissipation processes are not relevant in our experimental conditions and that, depending on the density of nodes in the networks, fracture occurs in the linear viscoelastic regime or in a nonlinear regime. In addition, analysis of the crack opening profiles indicates deviations from a parabolic shape close to the crack tip for weakly connected networks. We demonstrate a direct correlation between the amplitude of the deviation from the parabolic shape and the amount of nonlinear viscoelasticity [1].(ii) For a Hele-Shaw cell geometry based on the injection of a low viscosity fluid into the viscoelastic material confined between two plates, we show
that cracks nucleate when the sample deformation rate involved is
comparable to the inverse of the shortest relaxation time scale of the networks. For a double network, significant rearrangements of the micelles occur as a crack nucleates and propagates. We show that birefringence develops at the crack tip over a finite length, ξ, which corresponds to the length scale over which micelle alignment occurs. We find that ξ is larger for slower cracks, suggesting an increase of ductility.
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